Product ID:SPRAY PAINTS, 7830 DEERE GREEN
MSDS Date:06/01/1995
FSC:8010
NIIN:00N052866
MSDS Number: CDTHP

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: MART2

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

760

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 14%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

22

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 23%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

7.1

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 8%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

180

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 17%

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/1000STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER;

CAS: 763-69-9

RTECS: UF3325000

Fraction By Weight: 4%

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 2-3%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

82.3% BY WEIGHT

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO

RTECS: 9999999ZZ

THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONSULT

RTECS: 9999999ZZ

LIST INFORMATION & SAFE HANDLING & EXPOSURE

RTECS: 9999999ZZ

CONSULT NFPA CODE. USE APPRVD BONDING &

RTECS: 9999999ZZ

INCIN/EXPOSE TO TEMP > 120F. HEAT FROM SUNLIGHT,

RTECS: 9999999ZZ

COULD CAUSE CONTR TO BURST. DO NOT TAKE INTERNALLY.

RTECS: 9999999ZZ

BY DELIBERATELY CONCENTRATING & INHALING CONTENTS

RTECS: 9999999ZZ

BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES.

RTECS: 9999999ZZ

NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ

RTECS: 9999999ZZ

LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ALCOHOLS & ACETATES CAN BE ABSORBED
THRU SKIN. ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV
SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. SIGNS
& SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, & LOSS OF COORD ARE
INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCH/BURNING (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SENSATION MAY INDICATE EYE/EXCESS
SKIN EXPOS. CHRONIC: PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE
EFTS TO LIVER, URINARY, BLOOD-FORM, CARDIO-VASCULAR, & REPRO SYS.
RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG
CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE.
(ING 10)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: REMOVE FROM EXPOS. RESTORE BRTHG. KEEP WARM & QUIET.
SKIN: WASH AFFECTED AREA THORO W/SOAP & WATER. REMOVE CONTAM CLTHG
& LAUNDER BEFORE REUSE. EYES: FLUSH W/LGE AMTS OF WATER FOR AT
LEAST 15 M IN. GET MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH
TO AN UNCON PERS. DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF
WATER. SEEK MED ATTN.

Flash Point Method:PMCC
Flash Point:-20F,-29C
Lower Limits:0.7%
Upper Limits:10.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ ARE
PREF. WATER MAY BE USED TO COOL CLSD (SUP DAT)
Unusual Fire/Explosion Hazard:KEEP CONTR TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS, & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:FOLLOW RECS FOR PROPER USE, VENT, &
PERS PROT EQUIP TO MIN EXPOS. CONTENTS ARE EXTREMELY FLAMM. KEEP
AWAY FROM HEAT, SPKS, & OPEN FLAME.
Other Precautions:VAPS WILL ACCUM READILY & MAY IGNITE EXPLO. DURING
USE & UNTIL ALL VAPS ARE GONE: KEEP AREA VENTD - DO NOT SMOKE -
EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS - TURN OFF STOVES, ELEC
TOOLS & APPLIANCES , & ANY OTHER SOURCES OF IGNIT. (ING 13)

Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD
BY NIOSH FOR PROT. WHEN SANDING, WIREBRUSHING, ABRADING,
BURNING/WELDING DRIED FILM, WEAR PARTICULATE RESP APPRVD (SUP DAT)
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE (ING 19)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC: CONTR TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO
WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQUIRES SPECIAL
PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ
. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. RESP PROT: BY
NIOSH FOR PROT AGAINST NON-VOLATILE MATLS.

Boiling Pt:B.P. Text:<360F,<182C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

Waste Disposal Methods:WASTE MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR
261. WASTE MUST BE TESTED FOR IGNIT TO DETERMINE APPLIC EPA HAZ
WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CONTR. DISP OF I/A/W FED,
STATE, & LOC REGS REGA RDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.